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一个新的满足未来排放标准的摩托车尾气净化催化剂

王苏宁 , 崔亚娟 , 兰丽 , 史忠华 , 赵明 , 龚茂初 , 方瑞梅 , 陈思洁 , 陈耀强

催化学报 doi:10.1016/S1872-2067(14)60092-9

采用共沉淀法制备CeO2-ZrO2-La2O3-PrO2-Al2O3复合氧化物载体材料,以浸渍法制备了Pd-Rh, Pt-Rh和Pt-Pd-Rh型整体式催化剂.用N2吸附-脱附、程序升温还原、储氧量和X射线衍射对其进行了表征,并考察了老化前后催化剂的空燃比特性、空速特性和温度特性.结果表明,在三种催化剂中, Pt-Pd-Rh型催化剂表现出更优异的性能.在40000 h-1空速下,新鲜Pt-Pd-Rh型催化剂对C3H8, CO和NO的起燃温度T50分别为239,187和191oC,ΔT (T90-T50)分别为21,3和3oC.老化后, C3H8, CO和NO的T50分别为298,203和223oC,ΔT分别为22,5和13oC,且老化前后空燃比窗口较宽,适合于未来排放标准的摩托车尾气净化.

关键词: 摩托车尾气净化 , 整体式催化剂 , 铂-钯-铑 , 空燃比特性 , 空速特性 , 温度特性

Temperature Characteristics of Surface Acoustic Waves Propagating on La3Ga5SiO4 Substrates

Guowei ZHANG , Wenkang SHI , Xiaojun JI , Tao HAN , Feng DU , Lianger LI

材料科学技术(英)

Langasite (LGS) is a novel piezoelectric crystal. The authors numerically analyses the temperature stability of surface acoustic waves (SAW) and the relation of SAW propagation with temperature on certain optimal cuts on LGS in this paper. The results show that LGS has better temperature stability than traditional piezo crystals. The results also demonstrate that the velocity of SAW decrease with temperature, the electro-mechanical coupling constant (k2) and temperature coefficient of frequency increases parabolically and the power flow angle increases linearly on certain optimal cuts of LGS. The calculation result compared with the experimental and show good agreement.

关键词: La3Ga5SiO4(LGS) , null , null

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